Synthesis and Structure of the Octanuclear Manganese(II) Cage [(-Cp)Mn{2-NH(4,6-Me2pm)}·Mn{2-N(4,6-Me2
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- 作者：Carmen Soria Aluarez ; Andrew D. Bond ; Eilis A. Harron ; Richard A. Layfield ; Judith A. McAllister ; Christopher M. Pask ; Jeremy M. Rawson ; and Dominic S. Wright
- 刊名：Organometallics
- 出版年：2001
- 出版时间：October 1, 2001
- 年：2001
- 卷：20
- 期：20
- 页码：4135 - 4137
- 全文大小：71K
- 年卷期：v.20,no.20(October 1, 2001)
- ISSN：1520-6041
文摘
The 1:1 reaction of 2-NHB>2(4,6-Me2pm) withCp2Mn in thf gives the novel heteroleptic imido/amidoMn(II) cage [(
-Cp)Mn{2-NH(4,6-Me2pm)}·Mn{2-N(4,6-Me2pm)}]4 (1), composed of a central Mn(II) imido[Mn4{2-N(4,6-Me2pm)}4] core coordinated at the periphery by four [(-Cp)Mn{2-NH(4,6-Me2pm)}] monomerunits.
-Cp)Mn{2-NH(4,6-Me2pm)}·Mn{2-N(4,6-Me2pm)}]4 (1), composed of a central Mn(II) imido[Mn4{2-N(4,6-Me2pm)}4] core coordinated at the periphery by four [(-Cp)Mn{2-NH(4,6-Me2pm)}] monomerunits.