Highly Active Anti-Diabetic Metal–Organic Framework
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- 作者：David Briones ; Belén Fernández ; Antonio J. Calahorro ; David Fairen-Jimenez ; Raúl Sanz ; Fernando Martínez ; Gisela Orcajo ; Eider San Sebastián ; José M. Seco ; Cristina Sánchez González ; Juan Llopis ; Antonio Rodríguez-Diéguez
- 刊名：Crystal Growth & Design
- 出版年：2016
- 出版时间：February 3, 2016
- 年：2016
- 卷：16
- 期：2
- 页码：537-540
- 全文大小：317K
- ISSN：1528-7505
文摘
We have synthesized a novel zinc metal–organic framework (MOF) under mild hydrothermal routes using 5-aminotetrazole and methyl-2-amino-4-isonicotinate anionic ligands. The MOF exhibits a three-dimensional structure with intense blue-greenish photoluminescence emission at room temperature in the solid state. The luminescence, porosity, and adsorption capacity for CO2 and H2 of the Zn-based MOF have been fully determined using a combination of computational methods and experimental techniques. The synthesized Zn-based compound in this study exhibited a remarkable in vivo anti-diabetic activity and low in vitro cell toxicity.