Distinct Temperature-Dependent CO2 Sorption of Two Isomeric Metal鈥揙rganic Frameworks

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• 作者：Bo Liu ; Jingtao Shi ; Ke-Fen Yue ; Dong-Sheng Li ; Yao-Yu Wang
• 刊名：Crystal Growth & Design
• 出版年：2014
• 出版时间：April 2, 2014
• 年：2014
• 卷：14
• 期：4
• 页码：2003-2008
• 全文大小：449K
• 年卷期：v.14,no.4(April 2, 2014)
• ISSN：1528-7505

文摘

Two isomeric metal鈥搊rganic frameworks, consisting of Co-triazolate layers and positional isomeric dicarboxylate pillars, both show distinct temperature-dependent CO₂ sorption behaviors. Because of the pores functionalized by amino groups, both materials have high CO₂ uptake and highly selective sorption of CO₂ over CH₄ and N₂.