Iron-Catalyzed Aerobic Oxidation of Allylic Alcohols: The Issue of C鈺怌 Bond Isomerization

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• 作者：Jinxian Liu ; Shengming Ma
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：October 18, 2013
• 年：2013
• 卷：15
• 期：20
• 页码：5150-5153
• 全文大小：241K
• 年卷期：v.15,no.20(October 18, 2013)
• ISSN：1523-7052

文摘

An aerobic oxidation of allylic alcohols using Fe(NO₃)₃路9H₂O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined 伪,尾-unsaturated enals or enones with the retention of the C鈥揅 double-bond configuration.