Microwave Synthesis of Benchmark Organo-Iron Complexes

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• 作者：Sean M. Garringer ; Andrew J. Hesse ; John R. Magers ; Kristopher R. Pugh ; Stacy A. O’ ; Reilly ; Anne M. Wilson
• 刊名：Organometallics
• 出版年：2009
• 出版时间：December 14, 2009
• 年：2009
• 卷：28
• 期：23
• 页码：6841-6844
• 全文大小：693K
• 年卷期：v.28,no.23(December 14, 2009)
• ISSN：1520-6041

文摘

Microwave-assisted reaction techniques have been applied to the formation of a variety of organo-iron species. The species synthesized include ferrocene and acetylferrocene, piano stool complexes such as CpFe(CO)₂I, CpFe(PPh₃)(CO)I, and CpFe(PPh₃)(CO)(COMe), and bisphosphine iron complexes. The use of microwave-assisted reactions has decreased reaction times while maintaining or improving yields as compared to traditional methods.