Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal–Organic Polyhedra

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• 作者：Teng-Hao Chen ; Le Wang ; Jonathan V. Trueblood ; Vicki H. Grassian ; Seth M. Cohen
• 刊名：Journal of the American Chemical Society
• 出版年：2016
• 出版时间：August 3, 2016
• 年：2016
• 卷：138
• 期：30
• 页码：9646-9654
• 全文大小：657K
• 年卷期：0
• ISSN：1520-5126

文摘

A new strategy was developed by using a polymer ligand, poly(isophthalic acid)(ethylene oxide), to modulate the growth of metal–organic polyhedra (MOP) crystals. This macromolecular modulator can effectively control the crystal habit of several different Cub>24b>Lb>24b> (L = isophthalic acid derivatives) MOPs. The polymer also directed the formation of MOP structures under reaction conditions that only produce metal–organic frameworks in the absence of modulator. Moreover, the polymer also enabled the deposition of MOP crystals on glass surfaces. This macromolecular modulator strategy provides an innovative approach to control the morphology and assembly of MOP particles.