Iron Trichloride Mediated Allylation of Lithium Alkoxides through an Unusual Carbon-Oxygen Bond Cleavage

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• 作者：George W. Kabalka ; Min-Liang Yao ; Scott Borella ; Laura K. Goins
• 刊名：Organometallics
• 出版年：2007
• 出版时间：August 13, 2007
• 年：2007
• 卷：26
• 期：17
• 页码：4112 - 4114
• 全文大小：49K
• 年卷期：v.26,no.17(August 13, 2007)
• ISSN：1520-6041

文摘

Iron trichloride was found to cleave carbon-oxygenbonds in a variety of lithium alkoxides at room temperature.Other Lewis acids were also found to cleave the alkoxides. Acid-sensitive groups are tolerated under the reported reactionconditions.