Control of 1D Wave versus 2D Honeycomb CoIIICdIICuI Heterotrimetallic Architectures by ΔL−ΛL Diastereoisomerism of 详细信息    查看全文

• 作者：Takashi Aridomi ; Asako Igashira-Kamiyama ; Takumi Konno
• 刊名：Inorganic Chemistry
• 出版年：2008
• 出版时间：November 17, 2008
• 年：2008
• 卷：47
• 期：22
• 页码：10202-10204
• 全文大小：185K
• 年卷期：v.47,no.22(November 17, 2008)
• ISSN：1520-510X

文摘

The reactions of the Δ_L and Λ_L isomers of [Co(l-Hcys-N,S)(en)₂]²⁺ (l-H₂cys = l-cysteine) with CuCl in aqueous HCl gave Co^IIICu^I dinuclear complexes with the same S-bridged structures, Δ_L-1 and Λ_L-1. When Δ_L-1 was treated with CdCl₂ in water, a 1D wavelike (Co^III₂Cd^IICu^I)_n polymeric complex (2) was produced. On the other hand, similar treatment of Λ_L-1 led to the formation of a 2D honeycomb-like (Co^III₃Cd^II₃Cu^I)_n polymeric complex (3), supported by the presence of counter-monoanions.