Unleashing the Quadratic Nonlinear Optical Responses of Graphene by Confining White-Graphene (h-BN) Sections in Its Framework
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- 作者：Panaghiotis Karamanis ; Nicol谩s Otero ; Claude Pouchan
- 刊名：Journal of the American Chemical Society
- 出版年：2014
- 出版时间：May 21, 2014
- 年：2014
- 卷：136
- 期：20
- 页码：7464-7473
- 全文大小：701K
- 年卷期：v.136,no.20(May 21, 2014)
- ISSN：1520-5126
文摘
In an attempt to diversify the options in designing graphene-based systems bearing large second order nonlinear optical (NLO) responses of octupolar and/or dipolar character, the subject of the quadratic NLO properties of hybrid boron nitride (BN) graphene flakes is opened up. State of the art ab initio and density functional theory methods applied on a toolbox of book-text octupolar and arbitrary dipolar planar hybrid <i>hi>-BN鈥揼raphene nanosized systems reveal that by confining finite <i>hi>-BN sections in the internal network of graphene, the capacity of the 蟺-electron network of graphene species in delivering giant second order NLO responses could be fully exploited. Configuration interaction (CIS) and time-dependent density functional (TD) computations, within the sum-overstate (SOS) perturbational approach, expose that the prevailing (hyper)polarization mechanism, lying under the sizable computed octupolar hyperpolarizabilities, is fueled by alternating positive and negative atomic charges located in the internal part of the hybrid flakes, and more precisely at the BN/graphene intersections. This type of charge transfer mechanism distinguishes, in fact, the elemental graphene dipoles/octupoles we report here from other conventional NLO dipoles or octupoles. More interestingly, it is shown that by controlling the shape, size, and covering area of the <i>hi>-BN domain (or domains), one can effectively regulate 鈥溍?volont茅鈥?both the magnitudes and types of the second order NLO responses switching from dipolar to octupolar and vice versa. Especially in the context of the latter class of NLO properties, this communication brings into surface novel, graphene-based, octupolar planar or quasiplanar motifs. The take home message of this communication is summarized as follows: When the right BN segment is incorporated in the right section of the right graphene flake, systems of giant quadratic NLO octupolar and/or dipolar responses may emerge.