Facile Oxidative Addition of Aryl Iodides to Gold(I) by Ligand Design: Bending Turns on Reactivity

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• 作者：Maximilian Joost ; Abdallah Zeineddine ; Laura Est茅vez ; Sonia Mallet鈭扡adeira ; Karinne Miqueu ; Abderrahmane Amgoune ; Didier Bourissou
• 刊名：Journal of the American Chemical Society
• 出版年：2014
• 出版时间：October 22, 2014
• 年：2014
• 卷：136
• 期：42
• 页码：14654-14657
• 全文大小：308K
• ISSN：1520-5126

文摘

Thanks to rational ligand design, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered. The reaction proceeds under mild conditions and is general. The ensuing aryl gold(III) complexes have been characterized by spectroscopic and crystallographic means. DFT calculations indicate that the bending induced by the diphosphine ligand plays a key role in this process.