Natural Mineral-Based Solid Oxide Fuel Cell with Heterogeneous Nanocomposite Derived from Hematite and Rare-Earth Minerals

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• 作者：Chen Xia ; Yixiao Cai ; Yue Ma ; Baoyuan Wang ; Wei Zhang ; Mikael Karlsson ; Yan Wu ; Bin Zhu
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：August 17, 2016
• 年：2016
• 卷：8
• 期：32
• 页码：20748-20755
• 全文大小：539K
• 年卷期：0
• ISSN：1944-8252

文摘

Solid oxide fuel cells (SOFCs) have attracted much attention worldwide because of their potential for providing clean and reliable electric power. However, their commercialization is subject to the high operating temperatures and costs. To make SOFCs more competitive, here we report a novel and attractive nanocomposite hematite–LaCePrOx (hematite–LCP) synthesized from low-cost natural hematite and LaCePr-carbonate mineral as an electrolyte candidate. This heterogeneous composite exhibits a conductivity as high as 0.116 S cm^–1 at 600 °C with an activation energy of 0.50 eV at 400–600 °C. For the first time, a fuel cell using such a natural mineral-based composite demonstrates a maximum power density of 625 mW cm^–2 at 600 °C and notable power output of 386 mW cm^–2 at 450 °C. The extraordinary ionic conductivity and device performances are primarily attributed to the heterophasic interfacial conduction effect of the hematite–LCP composite. These superior properties, along with the merits of ultralow cost, abundant storage, and eco-friendliness, make the new composite a highly promising material for commercial SOFCs.