Indium(III) Acetate-Catalyzed Intermolecular Radical Addition of Organic Iodides to Electron-Deficient Alkenes

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• 作者：Katsukiyo Miura ; Mitsuru Tomita ; Junji Ichikawa ; Akira Hosomi
• 刊名：Organic Letters
• 出版年：2008
• 出版时间：January 3, 2008
• 年：2008
• 卷：10
• 期：1
• 页码：133 - 136
• 全文大小：70K
• 年卷期：v.10,no.1(January 3, 2008)
• ISSN：1523-7052

文摘

In the presence of phenylsilane and a catalytic amount of indium(III) acetate, organic iodides added to electron-deficient alkenes in ethanolat room temperature. Both simple and functionalized organic iodides were applicable to this reaction. A plausible reaction mechanism involvesthe formation of indium hydride species by hydride transfer from silicon to indium and an indium hydride-mediated radical chain process.