Measurement of the Md3+/Md2+ Reduction Potential Studied with Flow Electrolytic Chromatography

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• 作者：Atsushi Toyoshima ; Zijie Li ; Masato Asai ; Nozomi Sato ; Tetsuya K. Sato ; Takahiro Kikuchi ; Yusuke Kaneya ; Yoshihiro Kitatsuji ; Kazuaki Tsukada ; Yuichiro Nagame ; Matthias Sch盲del ; Kazuhiro Ooe ; Yoshitaka Kasamatsu ; Atsushi Shinohara ; Hiromitsu Haba ; Julia Even
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：November 4, 2013
• 年：2013
• 卷：52
• 期：21
• 页码：12311-12313
• 全文大小：202K
• 年卷期：v.52,no.21(November 4, 2013)
• ISSN：1520-510X

文摘

The reduction behavior of mendelevium (Md) was studied using a flow electrolytic chromatography apparatus. By application of the appropriate potentials on the chromatography column, the more stable Md³⁺ is reduced to Md²⁺. The reduction potential of the Md³⁺ + e^{鈥?/sup> 鈫?Md2+ couple was determined to be 鈭?.16 卤 0.05 V versus a normal hydrogen electrode.}