Synthesis of Substituted Styrenes and 3-Vinylphenols Using Ruthenium-Catalyzed Ring-Closing Enyne Metathesis

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• 作者：Kazuhiro Yoshida ; Kana Nishii ; Yuto Kano ; Shiro Wada ; Akira Yanagisawa
• 刊名：Journal of Organic Chemistry
• 出版年：2014
• 出版时间：May 2, 2014
• 年：2014
• 卷：79
• 期：9
• 页码：4231-4239
• 全文大小：431K
• 年卷期：v.79,no.9(May 2, 2014)
• ISSN：1520-6904

文摘

The synthesis of substituted styrenes 3 and 3-vinylphenols 9 was achieved by ring-closing enyne metathesis (RCEM)/dehydration of 7 and RCEM/tautomerization of 8, respectively. Those methods provide selective access to unique aromatic compounds and solve the problem of regioisomer formation.