Reductive Detriflylation of N-Triflylamides with Red-Al

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• 作者：Kazunori Miyamoto ; Md. Mahbubul Hoque ; Sayaka Ogasa
• 刊名：The Journal of Organic Chemistry
• 出版年：2012
• 出版时间：September 21, 2012
• 年：2012
• 卷：77
• 期：18
• 页码：8317-8320
• 全文大小：213K
• 年卷期：v.77,no.18(September 21, 2012)
• ISSN：1520-6904

文摘

Reduction of cis-N-triflylaziridines with 10 equiv of Red-Al in toluene at 鈭?0 to 0 掳C selectively afforded corresponding deprotected parent aziridines in good to high yields. N,N-Dialkyltriflylamides were also successfully cleaved under similar reaction conditions.