Chiral Ruthenium(II) Complexes as Supramolecular Building Blocks for Heterometallic Self-Assembly
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- 作者：Hasti Iranmanesh ; Kasun S. A. Arachchige ; Mohan Bhadbhade ; William A. Donald ; Jane Y. Liew ; Kenny T.-C. Liu ; Ena T. Luis ; Evan G. Moore ; Jason R. Price ; Hong Yan ; Jiajia Yang ; Jonathon E. Beves
- 刊名：Inorganic Chemistry
- 出版年：2016
- 出版时间：December 19, 2016
- 年：2016
- 卷：55
- 期：24
- 页码：12737-12751
- 全文大小：976K
- ISSN：1520-510X
文摘
A series of enantiopure ruthenium(II) polypyridyl complexes are reported that feature pendant pyridyl groups suitable for building larger self-assembled structures. The complexes are characterized in detail in solution using NMR spectroscopy, cyclic voltammetry, and photophysical methods and in the solid state using single-crystal X-ray crystallography. The complexes are luminescent, displaying long excited-state lifetimes that are quenched when the pendant pyridyl groups are protonated. Reaction with cadmium(II) ions results in the formation of a mixed-metal one-dimensional coordination polymer, which was characterized by single-crystal X-ray crystallography.