Preparation and Crystal Structure of Guest-Dependent Charge-Transfer Host System Using 1,1′-Bi-2-naphthol and 2-Chloro-5-methyl-benzoquinone

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• 作者：Yoshitane Imai ; Kensaku Kamon ; Takafumi Kinuta ; Nobuo Tajima ; Tomohiro Sato ; Reiko Kuroda ; Yoshio Matsubara
• 刊名：Crystal Growth & Design
• 出版年：2008
• 出版时间：October 1, 2008
• 年：2008
• 卷：8
• 期：10
• 页码：3493-3496
• 全文大小：223K
• 年卷期：v.8,no.10(October 1, 2008)
• ISSN：1528-7505

文摘

A guest-dependent charge-transfer (CT) host system was found that was composed of racemic (rac)-1,1′-bi-2-naphthol as an electron donor and 2-chloro-5-methyl-benzoquinone as an electron acceptor; in this complex, aromatic guests (benzene/toluene), electron-acceptor guests (tetrafluoro-1,4-benzoquinone (TF-BQ)), or alcohol guests (ethanol) can variously be included by changing the packing of electron-donor and -acceptor molecules. When ethanol was used as a guest, a chiral CT complex including ethanol was obtained.