Formation and Crystal Structure of Two-Component Host System Having Helical Chirality and Comprising 9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine and 1,1′-Binaphthyl-2,2′-dicarboxylic

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• 作者：Yoshitane Imai ; Katuzo Murata ; Kensaku Kamon ; Takafumi Kinuta ; Tomohiro Sato ; Reiko Kuroda ; Yoshio Matsubara
• 刊名：Crystal Growth & Design
• 出版年：2009
• 出版时间：January 7, 2009
• 年：2009
• 卷：9
• 期：1
• 页码：602-605
• 全文大小：200K
• 年卷期：v.9,no.1(January 7, 2009)
• ISSN：1528-7505

文摘

A two-component supramolecular host system having multiple chiral points (central, axial, and helical), which can include an n-alkyl alcohol molecule, was successfully formed by combining (11R,12R)-9,10-dihydro-9,10-ethanoanthracene-11,12-diamine with central chirality and (S)-1,1′-binaphthyl-2,2′-dicarboxylic acid with axial chirality. The helical chirality of this host system was induced by the central and axial chiralities of the component molecules in solid state.