Synthesis, Luminescence, and Electrochemistry of Mix-Capped Trinuclear Copper(I) Acetylide Complexes. X-ray Crystal Structures of [Cu3(
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文摘
Two luminescent mix-capped trinuclear copper(I) acetylide complexes, [Cu3(-dppm)3(3-1-CCC6H4OMe-p)(3-1-CCC6H4OEt-p)]PF6 (1) and [Cu3(-dppm)3(3-1-CCC6H4OMe-p)(2-1-CCC6H4NO2-p)]PF6 (2), have been synthesized and their photophysical andelectrochemical properties studied. The X-ray crystal structures of 1 and 2 have also beendetermined.

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