Synthesis of Luminescent Trinuclear Silver(I) Acetylides of Bis(diphenylphosphino)methane and Bis(diphenylphosphino)-n-propylamine. X-ray Crystal Structures of [Ag3(
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- 作者：Vivian Wing-Wah Yam ; Wendy Kit-Mai Fung ; and Kung-Kai Cheung
- 刊名：Organometallics
- 出版年：1997
- 出版时间：May 13, 1997
- 年：1997
- 卷：16
- 期：10
- 页码：2032 - 2037
- 全文大小：185K
- 年卷期：v.16,no.10(May 13, 1997)
- ISSN：1520-6041
文摘
A series of soluble trinuclear silver(I) complexes containingmonocapped and bicappedacetylides,[Ag3(LL)3(
3-
1-C
CR)]2+and[Ag3(LL)3(3-1-CC-C6H4-NO2-p)2]+[LL=[(C6H5)2P]2CH2 (dppm),[(C6H5)2P]2NnPr(nPrPNP)], have been synthesized. TheX-ray crystal structuresof[Ag3(-dppm)3(3-1-CC-C6H4-NO2-p)]2+and[Ag3(-dppm)3(3-1-CC-C6H4-NO2-p)2]+have been determined.
3-1-CCR)]2+and[Ag3(LL)3(3-1-CC-C6H4-NO2-p)2]+[LL=[(C6H5)2P]2CH2 (dppm),[(C6H5)2P]2NnPr(nPrPNP)], have been synthesized. TheX-ray crystal structuresof[Ag3(-dppm)3(3-1-CC-C6H4-NO2-p)]2+and[Ag3(-dppm)3(3-1-CC-C6H4-NO2-p)2]+have been determined.