Reaction of Arenes with Iodine in the Presence of Potassium Peroxodisulfate in Trifluoroacetic Acid. Direct and Simple Synthesis of Diaryliodonium Triflates

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• 作者：Md. Delwar Hossain ; Yasuyuki Ikegami ; Tsugio Kitamura
• 刊名：Journal of Organic Chemistry
• 出版年：2006
• 出版时间：December 22, 2006
• 年：2006
• 卷：71
• 期：26
• 页码：9903 - 9905
• 全文大小：49K
• 年卷期：v.71,no.26(December 22, 2006)
• ISSN：1520-6904

文摘

Diaryliodonium triflates have been directly prepared byreaction of arenes with elemental iodine in good yields byusing K₂S₂O₈ and TFA, followed by treatment with NaOTf.This procedure avoids the use of high temperature and severereaction conditions.