Recent Developments in Negishi Cross-Coupling Reactions

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• 作者：Diana Haas ; Jeffrey M. Hammann ; Robert Greiner ; Paul Knochel
• 刊名：ACS Catalysis
• 出版年：2016
• 出版时间：March 4, 2016
• 年：2016
• 卷：6
• 期：3
• 页码：1540-1552
• 全文大小：1105K
• ISSN：2155-5435

文摘

This Perspective describes general methods for the preparation of polyfunctional zinc organometallics and their use in Negishi cross-coupling reactions. Recent advances including new ligands and palladium catalysts are described. Related Negishi cross-coupling reactions involving Ni-, Cu-, Co-, and Fe-catalyzed cross-couplings are covered. The availability of a range of zinc organometallics combined with new efficient catalysts allows for efficient cross-coupling reactions with various organic electrophiles under usually mild conditions.