Self-Assembly of Polyhedral Indium鈥揙rganic Nanocages

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• 作者：Jinjie Qian ; Feilong Jiang ; Kongzhao Su ; Qipeng Li ; Daqiang Yuan ; Maochun Hong
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：December 1, 2014
• 年：2014
• 卷：53
• 期：23
• 页码：12228-12230
• 全文大小：291K
• ISSN：1520-510X

文摘

A synthetic strategy to construct discrete indium鈥搊rganic polyhedra has been illustrated based on small three-membered windows from a 2,5-pyridinedicarboxylate (PDC) ligand with an angle of 120掳. [Et<sub>2sub>NH<sub>2sub>]<sub>6sub>[In<sub>6sub>(PDC)<sub>12sub>] (InOF-10) is a high-symmetry octahedron with eight three-membered windows, and [Et<sub>2sub>NH<sub>2sub>]<sub>18sub>[In<sub>18sub>(BPDC)<sub>6sub>(PDC)<sub>30sub>] (InOF-11) is a complex polyhedron derived from 3-edge-removed octahedra with an auxiliary biphenyl-3,3鈥?dicarboxylate (BPDC) ligand. Moreover, the sorption behavior of the latter is also well investigated.