Homochiral Helical Metal鈥揙rganic Frameworks of Potassium

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• 作者：Daniel L. Reger ; Andrew P. Leitner ; Mark D. Smith
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：October 1, 2012
• 年：2012
• 卷：51
• 期：19
• 页码：10071-10073
• 全文大小：267K
• 年卷期：v.51,no.19(October 1, 2012)
• ISSN：1520-510X

文摘

Two trifunctional ligands built from enantiopure amino acids and containing a 1,8-naphthalimide group have been used to prepare two new complexes of potassium that have extended structures based on homochiral-rod secondary building units. One structure is a three-dimensional metal鈥搊rganic framework (MOF), while the other is a two-dimensional solid that is organized into a supramolecular MOF by strong 蟺路路路蟺-stacking interactions of the naphthalimide groups in the third dimension.