文摘
We presented the first exploration of the easily prepared nickel-decorated magnetic Fe<sub>3sub>O<sub>4sub> nanoparticles as recyclable nanosized magnetic self-stirring catalysts for microdroplet reactions. The cross-linked polymer poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) (PZS) was used as the intermediary to link Fe<sub>3sub>O<sub>4sub> and anchored nickel nanodots. On the basis of the charming magnetic feathers of Fe<sub>3sub>O<sub>4sub> and the fine catalysis activity of Ni, the Fe<sub>3sub>O<sub>4sub>@PZS-Ni nanoparticles could not only self-stir or make the reactants move along the tiny channels with the help of the external rotating magnetic field but also exhibit high catalysis activity and convenient recyclability. The Fe<sub>3sub>O<sub>4sub>@PZS-Ni nanoparticles have the merits of small size, good suspension, easy fabrication, and most importantly, superior flexibility and adaptability to any shape of the microreactors or nanoreactors; thus, they may bring new inspiration for self-stirring catalytic reactions in micro/nanochips or micro/nanobiological tubules or tissues.