Large-Size KCa0.8Sr0.2I3:Eu2+ Crystals: Growth and Characterization of Scintillation Properties

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• 作者：Yuntao Wu ; Adam C. Lindsey ; Mariya Zhuravleva ; Merry Koschan ; Charles L. Melcher
• 刊名：Crystal Growth & Design
• 出版年：2016
• 出版时间：July 6, 2016
• 年：2016
• 卷：16
• 期：7
• 页码：4129-4135
• 全文大小：505K
• 年卷期：0
• ISSN：1528-7505

文摘

The newly developed KCa_0.8Sr_0.2I₃:Eu²⁺ scintillator with 2.5% energy resolution at 662 keV shows great potential for use in gamma-ray spectroscopy applications, but progress toward large-size crystal growth has been hindered by cracking and inclusion problems. In this paper, we report a detailed study on the role of process variables of Bridgman growth, including grain selector designs, ampule surface treatments, and temperature gradients. It was found that crystal cracking can be effectively prevented by using a carbon-coated quartz ampule with a bent capillary. A high temperature gradient of 45 °C/cm at the solid–liquid interface can positively contribute to the suppression of the formation of visible inclusions caused by constitutional supercooling. By using optimized growth parameters, high quality 22 mm diameter KCa_0.8Sr_0.2I₃ single crystals doped with 0.5, 1, and 3 mol % Eu²⁺ and 38 mm diameter KCa_0.8Sr_0.2I₃ single crystals doped with 0.5 mol % Eu²⁺ were grown by the Bridgman method. The scintillation properties, including radioluminescence, light yield, energy resolution, and scintillation decay, of ϕ22 mm × 22 mm and ϕ38 mm × 35 mm samples were also investigated.