Templated Synthesis, Postsynthetic Metal Exchange, and Properties of a Porphyrin-Encapsulating Metal鈥揙rganic Material

详细信息    查看全文

• 作者：Zhenjie Zhang ; Linping Zhang ; Lukasz Wojtas ; Patrick Nugent ; Mohamed Eddaoudi ; Michael J. Zaworotko
• 刊名：The Journal of the American Chemical Society
• 出版年：2012
• 出版时间：January 18, 2012
• 年：2012
• 卷：134
• 期：2
• 页码：924-927
• 全文大小：281K
• 年卷期：v.134,no.2(January 18, 2012)
• ISSN：1520-5126

文摘

Reaction of biphenyl-3,4鈥?5-tricarboxylate (H₃BPT) and CdCl₂ in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal鈥搊rganic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd₆(BPT)₄Cl₄(H₂O)₄]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity.