Solid−Liquid Equilibria in Binary Mixtures of 1,8-Cineole with p-Cymene, β-Pinene, and Camphene
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  • 作者:Dongwei Wei ; Lishuo Wang ; Chao Zhang
  • 刊名:Journal of Chemical & Engineering Data
  • 出版年:2010
  • 出版时间:March 11, 2010
  • 年:2010
  • 卷:55
  • 期:3
  • 页码:1456-1458
  • 全文大小:108K
  • 年卷期:v.55,no.3(March 11, 2010)
  • ISSN:1520-5134
文摘
Solid−liquid equilibria have been measured for binary mixtures of 1,8-cineole with p-cymene, β-pinene, and camphene, respectively, using differential scanning calorimetry (DSC) over the whole composition concentration range. All three are simple eutectic systems. The eutectic point of the (1,8-cineole (1) + p-cymene (2)) mixture is at 200.0 K and x1 = 0.124, the (1,8-cineole (1) + β-pinene (2)) mixture at 205.6 K and x1 = 0.154, and the (1,8-cineole (1) + camphene (2)) mixture at 251.8 K and x1 = 0.582. An empirical equation of Ott and Goates was used for correlating the experimental data.

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