Self-Sufficient and Exclusive Oxygenation of Methane and Its Source Materials with Oxygen to Methanol via Metgas Using Oxidative Bi-reforming

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• 作者：George A. Olah ; G. K. Surya Prakash ; Alain Goeppert ; Miklos Czaun ; Thomas Mathew
• 刊名：The Journal of the American Chemical Society
• 出版年：2013
• 出版时间：July 10, 2013
• 年：2013
• 卷：135
• 期：27
• 页码：10030-10031
• 全文大小：178K
• 年卷期：v.135,no.27(July 10, 2013)
• ISSN：1520-5126

文摘

A combination of complete methane combustion with oxygen of the air coupled with bi-reforming leads to the production of metgas (H₂/CO in 2:1 mole ratio) for exclusive methanol synthesis. The newly developed oxidative bi-reforming allows direct oxygenation of methane to methanol in an overall economic and energetically efficient process, leaving very little, if any, carbon footprint or byproducts.