Oxidation of Shenfu Coal with RuO4 and NaOCl

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• 作者：Zi-Shuo Yao ; Xian-Yong Wei ; Jie Lv ; Fang-Jing Liu ; Yao-Guo Huang ; Jing-Jing Xu ; Fei-Jian Chen ; Yong Huang ; Yan Li ; Yao Lu ; Zhi-Min Zong
• 刊名：Energy & Fuels
• 出版年：2010
• 出版时间：March 18, 2010
• 年：2010
• 卷：24
• 期：3
• 页码：1801-1808
• 全文大小：946K
• 年卷期：v.24,no.3(March 18, 2010)
• ISSN：1520-5029

文摘

Shenfu coal (SFC) oxidation with RuO₄ and NaOCl were studied and compared. Most of organic matter in SFC was converted into soluble species with either of the oxidants. Benzene polycarboxylic acids (BPCAs) and alkanoic acids (AAs) are the main products from the reactions. The products from SFC oxidation with RuO₄ are rich in long-chain AAs, whereas those with NaOCl predominantly consist of chloro-substituted short-chain AAs and BPCAs. The related reaction mechanisms are discussed according to the experimental results.