d鈭抐 Heterobimetallic Association between Ytterbium and Ruthenium Carbon-Rich Complexes: Redox Commutation of Near-IR Luminescence

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• 作者：Emmanuel Di Piazza ; Lucie Norel ; Karine Costuas ; Adrien Bourdolle ; Olivier Maury ; St茅phane Rigaut
• 刊名：Journal of the American Chemical Society
• 出版年：2011
• 出版时间：April 27, 2011
• 年：2011
• 卷：133
• 期：16
• 页码：6174-6176
• 全文大小：719K
• 年卷期：v.133,no.16(April 27, 2011)
• ISSN：1520-5126

文摘

We describe how the association between an ytterbium ion and a ruthenium carbon-rich complex enables the first switching of the near-IR Yb(III) luminescence by taking advantage of the redox commutation of the carbon-rich antenna.