Redox Modulation of Magnetic Slow Relaxation in a 4f-Based Single-Molecule Magnet with a 4d Carbon-Rich Ligand

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• 作者：Lucie Norel ; Min Feng ; Kevin Bernot ; Thierry Roisnel ; Thierry Guizouarn ; Karine Costuas ; St茅phane Rigaut
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：March 3, 2014
• 年：2014
• 卷：53
• 期：5
• 页码：2361-2363
• 全文大小：191K
• 年卷期：v.53,no.5(March 3, 2014)
• ISSN：1520-510X

文摘

A ruthenium carbon-rich-based ligand that brings redox reversibility to a dysprosium-based single-molecule magnet is reported. Long-distance perturbation of the 4f ion is achieved upon oxidation, resulting in an overall enhancement of the magnetic slow relaxation.