Carbon Monoxide Activation via O-Bound CO Using Decamethylscandocinium鈥揌ydridoborate Ion Pairs
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- 作者：Andreas Berkefeld ; Warren E. Piers ; Masood Parvez ; Ludovic Castro ; Laurent Maron ; Odile Eisenstein
- 刊名：The Journal of the American Chemical Society
- 出版年：2012
- 出版时间：July 4, 2012
- 年：2012
- 卷：134
- 期：26
- 页码：10843-10851
- 全文大小：446K
- 年卷期：v.134,no.26(July 4, 2012)
- ISSN：1520-5126
文摘
Ion pairs [Cp*2Sc]+[HB(p-C6F4R)3]鈭?/sup> (R = F, 1-F; R = H, 1-H) were prepared and shown to be unreactive toward D2 and 伪-olefins, leading to the conclusion that no back-transfer of hydride from boron to scandium occurs. Nevertheless, reaction with CO is observed to yield two products, both ion pairs of the [Cp*2Sc]+ cation with formylborate (2-R) and borataepoxide (3-R) counteranions. DFT calculations show that these products arise from the carbonyl adduct of the [Cp*2Sc]+ in which the CO is bonded to scandium through the oxygen atom, not the carbon atom. The formylborate 2-R is formed in a two-step process initiated by an abstraction of the hydride by the carbon end of an O-bound CO, which forms an 畏2-formyl intermediate that adds, in a second step, the borane at the carbon. The borataepoxide 3-R is suggested to result from an isomerization of 2-R. This unprecedented reaction represents a new way to activate CO via a reaction channel emanating from the ephemeral isocarbonyl isomer of the CO adduct.