Rational Assembly of Primitive Cubic Networks Using Hexameric Stacks of Sodium Aryloxides as Nodes
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- 作者：Dugald J. MacDougall ; Bruce C. Noll ; and Kenneth W. Henderson
- 刊名：Inorganic Chemistry
- 出版年：2005
- 出版时间：March 7, 2005
- 年：2005
- 卷：44
- 期：5
- 页码：1181 - 1183
- 全文大小：211K
- 年卷期：v.44,no.5(March 7, 2005)
- ISSN：1520-510X
文摘
The two sodium aryloxide complexes [{(4-R-C6H4ONa)6·(dioxane)3}
], where R = Et (1) or F (2), have been preparedand found to form three-dimensional cubic networks in the solidstate. Each structure is similarly composed of dioxane-connectedNa6O6 aggregates that act as octahedral nodes in directing theassembly process. Although the localized metrical parameters withinthe hexameric cages are similar to each other, as well as to thoseof the molecular analogue [(4-F-C6H4ONa)6·(THF)8] (3), the grossarchitectures show significant variations. In particular, the smallercomplex 2 ensures effective filling of space through transannularNa-F interaggregate interactions, resulting in substantial compression of the cubic framework.
], where R = Et (1) or F (2), have been preparedand found to form three-dimensional cubic networks in the solidstate. Each structure is similarly composed of dioxane-connectedNa6O6 aggregates that act as octahedral nodes in directing theassembly process. Although the localized metrical parameters withinthe hexameric cages are similar to each other, as well as to thoseof the molecular analogue [(4-F-C6H4ONa)6·(THF)8] (3), the grossarchitectures show significant variations. In particular, the smallercomplex 2 ensures effective filling of space through transannularNa-F interaggregate interactions, resulting in substantial compression of the cubic framework.