文摘
A 2D + 2D → 3D inclined polycatenated dynamic metal–organic framework of {[Cu(4-bpe)(2-ntp)(H<sub>2sub>O)<sub>2sub>]·2H<sub>2sub>O}<sub>nsub> [<b>1b>, where 2-ntp<sup>2–sup> = 2-nitroterephthalate and 4-bpe = 1,2-bis-(4-pyridyl)ethane] has been synthesized and characterized. The variable-temperature powder X-ray diffraction study indicates the dynamic nature of the inclined polycatenated framework, and the dehydrated framework with exposed metal centers exhibits excellent type I H<sub>2sub> adsorption of 1.94 wt % at 77 K and 1 bar of pressure.