Highly Selective Turn-On Fluorogenic Chemosensor for Robust Quantification of Zn(II) Based on Aggregation Induced Emission Enhancement Feature

详细信息    查看全文

• 作者：Milan Shyamal ; Prativa Mazumdar ; Samir Maity ; Sadhan Samanta ; Gobinda P. Sahoo ; Ajay Misra
• 刊名：ACS Sensor
• 出版年：2016
• 出版时间：June 24, 2016
• 年：2016
• 卷：1
• 期：6
• 页码：739-747
• 全文大小：709K
• ISSN：2379-3694

文摘

An incisively designed notable aggregation-induced emission enhancement (AIEE) active fluorescence probe, 1-(2-hydroxynaphthylmethylene)-2-(3-methoxy-2-hydroxybenzylidene) hydrazine (L), was synthesized via straightforward reaction from inexpensive reagents. It exhibited rapid response, superb selectivity, and swift sensitivity toward Zn<sup>2+sup> based on its promising CHEF/AIEE feature. L not only can sense Zn<sup>2+sup> through sharp colorimetric and selective turn-on fluorescence responses in DMF/H<sub>2sub>O (9:1, v/v) medium, but also can distinguish between its significant AIEE activity in high water ratio and Zn<sup>2+sup> triggered AIEE activity through individual emission signals. Intriguingly, the AIEE properties of L may improve its impact. The molecules of L are aggregated into ordered one-dimensional rod-shaped microcrystals that show an obvious optical waveguide effect. Job’s plot from UV–vis absorption revealed the formation of L-Zn<sup>2+sup> complex with 1:1 stoichiometry. When bound with Zn<sup>2+sup> in 1:1 mode, enhanced turn-on emission was observed via chelation enhanced fluorescence through sensor complex (L-Zn) formation and excess addition of Zn<sup>2+sup>, a vivid enhancement of fluorescence intensity over manifold through aggregate formation was observed. The entire process takes ∼5 s, i.e., faster response time. The probe can detect Zn<sup>2+sup> as low as 1.1 × 10<sup>–7sup> M. The AIEE mechanism of L and Zn<sup>2+sup> triggered AIEE mechanism were well established from fluorescence anisotropy, DLS, SEM, optical fluorescence microscope, time-resolved photoluminescence, and fluorescence reversibility study by adding Zn<sup>2+sup> and EDTA sequentially. Furthermore, the proposed analytical system with clear AIEE mechanism demonstrates a potential outlook for the on-site practical applications.