Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

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• 作者：Ole Mallow ; Jens Bolsinger ; Pamela Finke ; Malte Hesse ; Yu-Sheng Chen ; Andrew Duthie ; Simon Grabowsky ; Peter Luger ; Stefan Mebs ; Jens Beckmann
• 刊名：Journal of the American Chemical Society
• 出版年：2014
• 出版时间：August 6, 2014
• 年：2014
• 卷：136
• 期：31
• 页码：10870-10873
• 全文大小：244K
• ISSN：1520-5126

文摘

The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me₂NC₁₀H₆)₂TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me₂NC₁₀H₆)₂TeNC(O)CH₃ (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me₂NC₁₀H₆)₂Te(OH)]Cl.