Synthesis and Crystal Structure of the Rhenium(I) Tricarbonyl Complex of 5,10,15,20-Tetra-p-tolyl-21,23-dithiaporphyrin

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• 作者：Tejinder Kaur ; Avijit Ghosh ; Palanisamy Rajakannu ; Mangalampalli Ravikanth
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：March 3, 2014
• 年：2014
• 卷：53
• 期：5
• 页码：2355-2357
• 全文大小：215K
• 年卷期：v.53,no.5(March 3, 2014)
• ISSN：1520-510X

文摘

The hexacoordinated rhenium(I) complex of 5,10,15,20-tetra-p-tolyl-21,23-dithiaporphyrin was synthesized, and the crystal structure analysis revealed the unusual binding mode of rhenium(I) to two thiophene sulfur atoms and one of the pyrrole nitrogen atoms of the porphyrin macrocycle.