Conversion of CS2 to Thioaldehyde at a Single Iron Center
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- 作者：Natalie L. Cromhout ; John F. Gallagher ; Anthony R. Manning ; and Alexander Paul
- 刊名：Organometallics
- 出版年：1999
- 出版时间：March 29, 1999
- 年：1999
- 卷：18
- 期：7
- 页码：1119 - 1121
- 全文大小：126K
- 年卷期：v.18,no.7(March 29, 1999)
- ISSN：1520-6041
文摘
UV-irradiation of the thiocarbonyl complexFe(CO)2(CS){P(OPh)3}2, prepared from Fe(CO)2(CS2){P(OPh)3}2, affords the unstable thioaldehyde complexFe(CO)2{P(OPh)3}{(PhO)2P(OC6H4)C(H)S}, which reactswith P(OPh)3 to give Fe(CO){P(OPh)3}2{(PhO)2P(OC6H4)C(H)S}, the crystal structure of which reveals an 
2(C,S)-bonded thioaldehyde group formally derived from insertion of the thiocarbonyl C atom into an ortho C-H bondof an axially bound P(OPh)3 phenyl group.
2(C,S)-bonded thioaldehyde group formally derived from insertion of the thiocarbonyl C atom into an ortho C-H bondof an axially bound P(OPh)3 phenyl group.