Bilayer Molecular Metals Based on Dissymmetrical Electron Donors

详细信息    查看全文

• 作者：Sandrina Oliveira ; Jos茅 Ministro ; Isabel C. Santos ; Dulce Belo ; Elsa B. Lopes ; Sandra Raba莽a ; Enric Canadell ; Manuel Almeida
• 刊名：Inorganic Chemistry
• 出版年：2015
• 出版时间：July 20, 2015
• 年：2015
• 卷：54
• 期：14
• 页码：6677-6679
• 全文大小：263K
• ISSN：1520-510X

文摘

The electrocrystallization from solutions of cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF) in the presence of different anions X = ClO₄^{鈥?/sup>, PF₆鈥?/sup>, and I₃鈥?/sup>, affords a new type of 2D molecular metals with composition (CNB-EDT-TTF)₄X based on an unprecedented bilayer structure of the donors induced by effective head to head interdonor interactions through the nitrile groups, which is responsible for 2D metallic systems with unusual properties such as the higher band filling, larger effective mass of carriers, and almost degenerated double Fermi surfaces.}