Synthesis and Reactivity of Nonbridged Metal-Metal Bonded Rhodium and Iridium Phenanthroline-Based N2O2 Dimers
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- 作者：Maoqi Feng and Kin Shing Chan
- 刊名：Organometallics
- 出版年：2002
- 出版时间：June 24, 2002
- 年：2002
- 卷：21
- 期：13
- 页码：2743 - 2750
- 全文大小：115K
- 年卷期：v.21,no.13(June 24, 2002)
- ISSN：1520-6041
文摘
Nonbridged metal dimers of phenanthroline-based N2O2 ligands of rhodium and iridiumhave been synthesized from the reactions of metal hydrides with TEMPO (2,2',6,6'-tetramethylpiperidinyloxy). Modification of phenathroline ligands has led to more lipophilicmetal complexes. The oxidative additions of the metal dimers with methyl iodide, silane,and hydrogen have been studied.