Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols

详细信息    查看全文

• 作者：Marcello Bertoli ; Aldjia Choualeb ; Alan J. Lough ; Brandon Moore ; Denis Spasyuk ; Dmitry G. Gusev
• 刊名：Organometallics
• 出版年：2011
• 出版时间：July 11, 2011
• 年：2011
• 卷：30
• 期：13
• 页码：3479-3482
• 全文大小：811K
• 年卷期：v.30,no.13(July 11, 2011)
• ISSN：1520-6041

文摘

A series of pincer-type complexes of Os and Ru have been synthesized and investigated in catalytic alcohol dehydrogenation. The hydrides OsHCl(CO)[HN(C₂H₄PiPr₂)₂] and OsH₂(CO)[HN(C₂H₄PiPr₂)₂] possess good air, moisture, and thermal stability and are outstanding versatile dehydrogenation catalysts for primary alcohols for reactions of transfer hydrogenation, dehydrogenative coupling, and amine alkylation.