Isolation of a Stable 1-Iridabicyclo[3.2.0]hepta-1,3,6-triene and Its Reversible Transformation into an Iridacycloheptatriene

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• 作者：Margarita Paneque ; Manuel L. Poveda ; Nuria Rend&oacute ; n ; and Kurt Mereiter
• 刊名：Journal of the American Chemical Society
• 出版年：2004
• 出版时间：February 18, 2004
• 年：2004
• 卷：126
• 期：6
• 页码：1610 - 1611
• 全文大小：59K
• 年卷期：v.126,no.6(February 18, 2004)
• ISSN：1520-5126

文摘

Reaction of the iridacyclopentadiene complex 2 with 2-butyne yields a mixture in equilibrium of the iridacycloheptatriene 3 and a novel 1-iridabicyclo[3.2.0]hepta-1,3,6-triene, 4.