An Illustration of the Limit of the Metal Organic Framework's Isoreticular Principle Using a Semirigid Tritopic Linker Obtained by "Click" Chemistry

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• 作者：Thomas Devic ; Olivier David ; Marion Valls ; Jé ; rô ; me Marrot ; Franç ; ois Couty ; Gé ; rard Fé ; rey
• 刊名：Journal of the American Chemical Society
• 出版年：2007
• 出版时间：October 24, 2007
• 年：2007
• 卷：129
• 期：42
• 页码：12614 - 12615
• 全文大小：143K
• 年卷期：v.129,no.42(October 24, 2007)
• ISSN：1520-5126

文摘

A new nitrogen-rich tricarboxylate linker was prepared by "click" chemistry and used for the preparation of a lanthanum-based open metal organic framework. This latter is built of inorganic 1-D rods connected through the tritopic linkers and illustrates one limit of the isoreticular principle, which is related to the partial flexibility of the linkers.