A Cubic, 12-Connected, Microporous Metal鈭扥rganometallic Phosphate Framework Sustained by Truncated Tetrahedral Nodes

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• 作者：Sayon A. Kumalah Robinson ; Marion-Vincent L. Mempin ; Amy J. Cairns ; K. Travis Holman
• 刊名：Journal of the American Chemical Society
• 出版年：2011
• 出版时间：February 16, 2011
• 年：2011
• 卷：133
• 期：6
• 页码：1634-1637
• 全文大小：734K
• 年卷期：v.133,no.6(February 16, 2011)
• ISSN：1520-5126

文摘

A rare example of a microporous metal鈭抩rganic phosphate, [Co₁₂(L)₆(渭₃-PO₄)₄(渭₃-F)₄(渭-H₂O)₆][NO₃]₂ (1), is synthesized by the reaction of a [(畏⁵-C₅H₅)Fe^II]⁺-functionalized terephthalate ligand with Co(NO₃)₂路6H₂O and phosphate and fluoride ions generated from the in situ hydrolysis of hexafluorophosphate. 1 is a cubic, 12-connected, face-centered cubic framework sustained by the linear connection of unprecedented, dodecanuclear truncated tetrahedral coordination clusters.