Multiparticle Exciton Ionization in Shallow Doped Carbon Nanotubes
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- 作者：Jay D. Sau ; Jared J. Crochet ; Stephen K. Doorn ; Marvin L. Cohen
- 刊名：The Journal of Physical Chemistry Letters
- 出版年：2013
- 出版时间：March 21, 2013
- 年：2013
- 卷：4
- 期：6
- 页码：982-986
- 全文大小：277K
- 年卷期：v.4,no.6(March 21, 2013)
- ISSN：1948-7185
文摘
Shallow hole doping in small-diameter semiconducting carbon nanotubes with a valley degeneracy is predicted to result in the resonant ionization of excitons into free electron鈥揾ole pairs. This mechanism, which relies on the chirality of the electronic states, causes excitons to decay with high efficiencies where the rate scales as the square of the dopant density. Moreover, multiparticle exciton ionization can account for delocalized fluorescence quenching when a few holes per micrometer of tube length are present.