Characterization of the Bis-Silylated Endofullerene Sc3N@C80

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• 作者：Takatsugu Wakahara ; Yuko Iiduka ; Ozora Ikenaga ; Tsukasa Nakahodo ; Akihiro Sakuraba ; Takahiro Tsuchiya ; Yutaka Maeda ; Masahiro Kako ; Takeshi Akasaka ; Kenji Yoza ; Ernst Horn ; Naomi Mizorogi ; Shigeru Naga
• 刊名：Journal of the American Chemical Society
• 出版年：2006
• 出版时间：August 2, 2006
• 年：2006
• 卷：128
• 期：30
• 页码：9919 - 9925
• 全文大小：545K
• 年卷期：v.128,no.30(August 2, 2006)
• ISSN：1520-5126

文摘

The photochemical reaction of Sc₃N@C₈₀ with 1,1,2,2-tetramesityl-1,2-disilirane affords the adductas a bis-silylated product. The adduct was characterized by NMR spectroscopy and single-crystal X-raystructure analysis. The dynamic behavior of the disilirane moiety and the encapsulated Sc₃N cluster werealso investigated. The unique redox property of the adduct is reported by means of CV and DPV.Experimental results were confirmed by density functional calculations.