Property and Reactivity of Fluoro(silyl)acetylenes and Fluoro(stannyl)acetylenes

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• 作者：Masahiro Shiosaki ; Masashi Unno ; Takeshi Hanamoto
• 刊名：Journal of Organic Chemistry
• 出版年：2010
• 出版时间：December 3, 2010
• 年：2010
• 卷：75
• 期：23
• 页码：8326-8329
• 全文大小：700K
• 年卷期：v.75,no.23(December 3, 2010)
• ISSN：1520-6904

文摘

Fluoro(silyl)acetylenes and fluoro(stannyl)acetylenes underwent a radical addition reaction of THF to furnish the corresponding fluorinated cyclic ethers in moderate to good yields. These intriguing addition reaction proved to proceed via a radical reaction mechanism.