Copper-Catalyzed Synthesis of Mixed Alkyl Aryl Phosphonates

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• 作者：Mart铆n Fa帽an谩s-Mastral ; Ben L. Feringa
• 刊名：Journal of the American Chemical Society
• 出版年：2014
• 出版时间：July 16, 2014
• 年：2014
• 卷：136
• 期：28
• 页码：9894-9897
• 全文大小：293K
• ISSN：1520-5126

文摘

Copper-catalysis allows the direct oxygen-arylation of dialkyl phosphonates with diaryliodonium salts. This novel methodology proceeds with a wide range of phosphonates and phosphoramidates under mild conditions and gives straightforward access to valuable mixed alkyl aryl phosphonates in very good yields and near perfect selectivity.