Organic Vapor Triggered Repeatable On鈥揙ff Crystalline-State Luminescence Switching

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• 作者：Kensuke Naka ; Takuji Kato ; Seiji Watase ; Kimihiro Matsukawa
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：April 16, 2012
• 年：2012
• 卷：51
• 期：8
• 页码：4420-4422
• 全文大小：240K
• 年卷期：v.51,no.8(April 16, 2012)
• ISSN：1520-510X

文摘

A nonporous crystalline solid consisting of an organoarsenic platinum(II) complex, i.e., a mononuclear diiodoplatinum(II) complex trans-PtI₂(cis-DHDAtBu)₂ (1) with cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine (cis-DHDAtBu), shows on鈥搊ff solid-state luminescence switching through reversible solvent vapor uptake and escape. The on鈥搊ff switching of solid-state luminescence was achieved without changing the structure or electronic state of the organoarsenic platinum(II) complex.